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CSIRO GASLAB - CO2C13 Carbon Dioxide Isotope Analysis datasets - Global Atmospheric Sampling Laboratory - Flask Sampling Network

The CSIRO Global Atmospheric Sampling Laboratory (GASLAB) Flask Sampling Network archive for the carbon 13 isotope (C13) of atmospheric trace gas carbon dioxide (CO2) concentrations. GASLAB principally analyzes air samples that have been captured at eleven fixed geographic sites and one moving (aircraft over bass strait and Cape Grim), but also includes other sites at various locations globally on a less regular or as needed basis. The CO2C13 measurements are made by concentrating the CO2 from the air sample utilising a 3 step automated cryogenic trapping system connected to a dual inlet stable isotope ratio mass spectrometer (Finnigan MAT252) for analysis. The CO2 and N2O gas chromatography concentrations data for the sample are used for ion corrections on the stable isotope measurements. Alternatively the Cape Grim in situ air sample (cia) which has already had the trapping process applied to it on site, uses the data from the Cape Grim in situ CO2 analyser, with the N2O concentration determined by interpolation from the CSIRO global flask network data. There are 6 differant types of flask that are used to store and transport air samples from site and in the labratory:(i) glass 0.5 litre ("G050"), (ii) glass 5.0 litre ("G500"), (iii) glass 0.8 litre ("G080"), (iv) electropolished stainless steel 1.6 litre "Sirocans" ("S160"), (v) glass 2.0 litre, 1 stopcopck ("F", "FF", "FA", "FE", "EP", ALT"), (vi) glass 2.0 litre, 2 stopcocks(“M1”, “S”, “P2”, “TEMP”). Files containing a single species value for each sample are denoted by a filename of the form (XXX_XXXX_event.XXX), for the geographically fixed sites data is also provided in the form of monthly means (e.g. XXX_XXXX_mm.XXX) with all files being in ascii format.

Simple

Identification info

Date
Citation identifier
Marlin Record Number: 8385

Citation identifier
Anzlic Identifier: ANZCW0306008385

Credit

CSIRO - Marine and Atmospheric Research (CMAR), Australian Bureau of Meteorology (BoM), Australian Antarctic Division (AAD), Australian Institute of Marine Science (AIMS), National Oceanic and Atmospheric Administration (NOAA), Environment Canada (EC).

Credit

Collin Allison(CSIRO)

Credit

Paul Krummel (CSIRO)

Credit

Paul Steele (CSIRO).

Status
On going
Point of contact
Role Organisation Electronic mail address
Point of contact

CSIRO Oceans & Atmosphere - Aspendale

Topic category
  • Climatology, meteorology, atmosphere

Extent

N
S
E
W




Temporal extent

Time period
1990-01
Title

•Allison, C. E., and R.J. Francey, 1995. High precision stable isotope measurements of atmospheric trace gases, in Reference and intercomparison materials for stable isotopes of light elements: proceedings of a consultants meeting, Vienna (IAEA-TECDOC-825). Vienna, Austria: International Atomic Energy Agency. p. 131-153.

•Allison, C.E., and R.J. Francey, 1999. d13C of atmospheric CO2 at Cape Grim: The CGA record, air standards and the CG92 reference scale in Baseline Atmospheric Program (Australia) 1996, edited by J.L. Gras, N. Derek, N.W. Tindale and A.L. Dick, pp. 45-56, Bureau of Meteorology and CSIRO Atmospheric Research, Melbourne, Australia.

•Allison, C.E., and R. J. Francey, 2007. Verifying southern hemisphere trends in atmospheric carbon dioxide stable isotopes, J. Geophys. Res., accepted.

•Thoning et al., 1989.

•Cooper, L.N., L.P. Steele, R.L. Langenfelds, D.A. Spencer and M.P. Lucarelli. Atmospheric methane, carbon dioxide, hydrogen, carbon monoxide and nitrous oxide from Cape Grim flask air samples analysed by gas chromatography. Baseline Atmospheric Program (Australia) 1996, edited by J.L. Gras, N. Derek, N.W. Tindale and A.L. Dick, pp 98 - 102, Bureau of Meteorology and CSIRO Atmospheric Research, Melbourne, Australia, 1999.

•CSIRO's global sampling network, sampling and analytical techniques (Francey et al., 1996).

•Measurement uncertainty (Langenfelds et al., 2003).

Date (Publication)
1995
Maintenance and update frequency
Continual
GCMD Keywords
  • Earth Science | Atmosphere | Atmospheric Chemistry | Carbon And Hydrocarbon Compounds | Carbon Dioxide
CSIRO Equipment
  • Mass Spectrometers
AODN Geographic Extent Names
  • Global / Oceans | World
CSIRO Source List
  • Observational: Aspendale - GASLAB

Resource constraints

Other constraints

Available for CSIRO internal use, users are required to contact Colin Allison, Paul Steele or Paul Krummel first.

Language
English
Character encoding
UTF8
Environment description

Data is in ASCII format, can be opened by any text editor or specialised programs such as IDL (ITTVIS), ARCview reader (freeware).

Supplemental Information

ATTRIBUTE STATEMENT:

Sites/dates "event" data is available for:

aia : 19/07/90-28/09/00, aia : 19/07/90-28/09/00, alc : 05/01/90-20/03/08, ama : 25/10/94-02/10/98, ama : 25/10/94-02/10/98, asa : 14/09/94-14/09/94, bhz : 05/06/98-12/01/03, bwu : 27/07/90-31/03/93, cfa : 28/08/90-01/05/08, cga : 06/06/90-11/07/08, cia : 09/03/90-23/06/08, cja : 24/08/00-09/07/08, cpu : 10/06/90-08/02/97, cri : 13/02/93-15/10/02, csa : 19/07/94-31/03/06, cya : 25/11/96-07/01/08, daa : 16/10/90-21/12/98, dva : 10/03/94-03/03/95, epc : 17/06/93-12/01/02, frc : 04/05/90-12/03/93, ice : 05/05/95-01/01/97, jba : 21/03/91-09/05/91, lda : 29/10/04-31/10/04, maa : 29/01/90-14/01/08, mba : 08/08/94-01/12/98, mis : 01/01/04-24/07/08, mix : 01/11/00-01/11/00, mlu : 07/09/90-05/06/08, mpa : 16/10/90-24/03/93, mqa : 12/04/90-14/02/08, nea : 17/07/90-28/11/91, nru : 01/01/96-01/01/00, ota : 11/09/05-24/07/08, rva : 12/03/91-28/03/98, rva : 12/03/91-28/03/98, rvf : 14/05/91-15/05/91, rvf : 14/05/91-15/05/91, rvs : 18/01/95-01/02/95, rvs : 18/01/95-01/02/95, sis : 10/11/92-10/01/04, spu : 05/02/90-01/02/08, sub : 27/03/91-11/01/06, tac : 10/07/01-01/05/08, tst : 06/08/91-21/07/08.

Sites/dates Monthly Mean "mm" data is available for:

alc : 01/90-03/08, bhz : 06/98-09/02, cfa : 08/90-05/08, cga : 06/90-04/08, cia : 01/82-04/08, cri : 02/93-10/02, cya : 06/97-01/08, daa : 10/90-12/98, epc : 06/93-01/02, maa : 03/90-10/07, mlu : 09/90-04/08, mqa : 02/91-02/08, sis : 11/92-12/03, spu : 02/90-01/08.

Filename format: (same as used by NOAA/ESRL/GMD/CCGG)

eg. cga_02D0_event.c02c13 where

CGA:sitecode (Cape Grim), 02:GASLAB Identity (Aspendale), D:Discrete data, 0:sampling platform: (0=land, 1=ship, 2=aircraft, 3=tower), event:Event data from every collection event or mm for monthly mean, co2c13:Species identifier.

Variable listing:

YYYY (year), MM (month), Dec Date (decimal date), C13CO2 per mil (), SD12 (standard deviations for monthly means), SD1 (deviation of monthly mean from daily smooth curve), SD2 (standard deviation of residuals of each data

point about the smooth curve for that month), N (actual data points used in calculating SD2).

Principle Site Listing:

ALC – Alert, Canada (82° 27’N, 62° 31’W, 6 metres altitude)

CFA - Cape Ferguson, Australia (19° 17’S, 147° 03’E, 2 m)

CGA - Cape Grim, Australia (40° 41’S, 144° 41’E, 94 m)

CRI – Cape Rama, India (15° 05’N, 73° 50’E, 60 m)

CYA - Casey, Australia (66° 17’S, 110° 32’E, 51 m)

EPC – Estevan Point, Canada (49° 23’N, 126° 32’W, 39 m)

MAA – Mawson, Australia (67° 37’S, 62° 52’E, 32 m)

MLU – Mauna Loa, Hawaii, USA (19° 32’N, 155° 35’W, 3397 m)

MQA – Macquarie Island, Australia (54° 29’S, 158° 58’E, 12 m)

SIS – Shetland, Scotland (60° 10’N, 01° 10’W, 30 m)

SPU – South Pole, Antarctica (89° 59’S, 24° 48’W, 2810 m)

Other sites:

ASA - Aspendale(Aust), BHZ - Baring Head, BWU - Barrow, CIA - Cape Grim Insitu, (Aust), CPU - Cheeka Peak, CSA - Cape Schanck (Aust), DAA - Charles Point (Aust), DVA - Davis (Antarctica), FRC - Fraserdale (Canada), JBA - Jabiru, LDA - Law Dome Firn Air, MIS - Misc, MIX - Mixed, MPA - Myilly Point (Aust), MSA - Mount St Leonard (Aust), NEA - Methane Survey, NRU - Niwot Ridge (Colerad), OTA - Otways Basin (Aust), SUB - Subsample transfer, TAC - Tacos ICP, THU - Trinidad Head, TST - Test flask, FUJ - Tokyo Uni.

Aircraft:

AIA - AIRCRAFT BASS STRAIT / CAPE GRIM, AMA - AIRCRAFT MISC.

Ships:

RVA - R/V AURORA, RVF - R/V FRANKLIN, RVS - R/V SOUTHERN SURVEYOR.

Distribution Information

Distribution format
  • DIGITAL - Text Documents - ASCII

OnLine resource

Data Link

Link to CDIAC (Carbon Dioxide Information Analysis Center) homepage

OnLine resource

Data Link

Link to WDCGG (World Data Centre for Greenhouse Gases) homepage

OnLine resource

Name of the resource

Project Data Location

Description

\\Gl-as\Gold\Data\CSIRO\co2c13\

Data quality info

Hierarchy level
Dataset

Report

Result

Date (Publication)
Explanation

N/A

Report

Result

Date (Publication)
Explanation

N/A

Report

Result

Date (Publication)
Explanation

Datasets for the 11 principle sites are the most complete. Others acquired on an "as need" basis.

Resource lineage

Statement

Ion corrections applied to stable isotope measurements using CO2 and N2O measurements taken by gas chromatography with FID & ECD detectors. Results adjusted onto the VPDB-CO2 scale. Flask data are assigned flags to indicate whether they are classified as retained or rejected. Monthly means are calculated as the mean of daily values from a smooth curve fit to the data using the curve-fitting routines described by Thoning et al. (1989).

Hierarchy level
Dataset

Metadata

Metadata identifier
2937fd5a-5dcb-49d8-861b-3874b12a4552

Language
English
Character encoding
UTF8
Contact
Role Organisation Electronic mail address
Point of contact

CSIRO Oceans & Atmosphere - Hobart

Metadata linkage

Point of truth URL of this metadata record

Point of truth URL of this metadata record

Date info (Creation)
2008-09-03T00:00:00
Date info (Revision)
2008-09-03T17:06:12

Metadata standard

Title

ISO 19115-3:2018

Title

Marine Community Profile

Date (Creation)
2019-05-30
Edition

3.0

Edition date
2019-05-30T00:00:00
Cited responsible party
Role Organisation Electronic mail address
Custodian

Marine Community Profile Governance Committee

 
 

Spatial extent

Keywords

CSIRO Equipment

Mass Spectrometers
CSIRO Source List

Observational: Aspendale - GASLAB
GCMD Keywords

Earth Science | Atmosphere | Atmospheric Chemistry | Carbon And Hydrocarbon Compounds | Carbon Dioxide


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